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Mark Webber s Red Bullem dokázal překonat svého týmového kolegu Sebastiana Vettela a zvítězil v kvalifikaci na Velkou cenu Španělska Formule 1. Třetí skončil Lewis Hamilton s McLarenem a čtvrtý domácí Fernando Alosno s Ferrari.
| P | # | Jezdec | Konstruktér | Q1 | Q2 | Q3 | K | |
|---|---|---|---|---|---|---|---|---|
| 1 | 2 | Mark Webber | Red Bull | 1:23.619 | 1:21.773 | 1:20.981 | 12 | |
| 2 | 1 | Sebastian Vettel | Red Bull | 1:24.142 | 1:21.540 | 1:21.181 | 13 | |
| 3 | 3 | Lewis Hamilton | McLaren | 1:24.370 | 1:22.148 | 1:21.961 | 12 | |
| 4 | 5 | Fernando Alonso | Ferrari | 1:23.485 | 1:22.813 | 1:21.964 | 15 | |
| 5 | 4 | Jenson Button | McLaren | 1:24.428 | 1:22.050 | 1:21.996 | 12 | |
| 6 | 10 | Vitaly Petrov | Renault | 1:23.069 | 1:22.948 | 1:22.471 | 14 | |
| 7 | 8 | Nico Rosberg | Mercedes | 1:23.507 | 1:22.569 | 1:22.599 | 14 | |
| 8 | 6 | Felipe Massa | Ferrari | 1:23.506 | 1:23.026 | 1:22.888 | 15 | |
| 9 | 12 | Pastor Maldonado | Williams | 1:23.406 | 1:22.854 | 1:22.952 | 14 | |
| 10 | 7 | Michael Schumacher | Mercedes | 1:22.960 | 1:22.671 | 12 | ||
| 11 | 18 | Sébastien Buemi | Toro Rosso | 1:23.962 | 1:23.231 | 6 | ||
| 12 | 17 | Sergio Pérez | Sauber | 1:24.209 | 1:23.367 | 9 | ||
| 13 | 19 | Jaime Alguersuari | Toro Rosso | 1:24.049 | 1:23.694 | 9 | ||
| 14 | 16 | Kamui Kobayashi | Sauber | 1:23.656 | 1:23.702 | 8 | ||
| 15 | 20 | Heikki Kovalainen | Lotus | 1:25.874 | 1:25.403 | 6 | ||
| 16 | 15 | Paul di Resta | Force India | 1:24.332 | 1:26.126 | 13 | ||
| 17 | 14 | Adrian Sutil | Force India | 1:24.648 | 1:26.571 | 0 | ||
| 18 | 21 | Jarno Trulli | Lotus | 1:26.521 | 0 | |||
| 19 | 11 | Rubens Barrichello | Williams | 1:26.910 | 0 | |||
| 20 | 24 | Timo Glock | Virgin | 1:27.315 | 0 | |||
| 21 | 23 | Vitantonio Liuzzi | HRT | 1:27.809 | 0 | |||
| 22 | 22 | Narain Karthikeyan | HRT | 1:27.908 | 0 | |||
| 23 | 25 | Jérôme D’Ambrosio | Virgin | 1:28.556 | 0 | |||
| 24 | 9 | Nick Heidfeld | Renault | 0 |
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