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Kvalifikaci na Velkou cenu Španělska vyhrál Lewis Hamilton s McLarenem. Na druhém místě skončil překvapivě Pastor Maldonado s Williamsem a třetí skončil domácí Fernando Alonso s Ferrari.
| P | # | Jezdec | Konstruktér | Q1 | Q2 | Q3 | K | |
|---|---|---|---|---|---|---|---|---|
| 1 | 4 | Lewis Hamilton | McLaren | 1:22.583 | 1:22.465 | 1:21.707 | 17 | |
| 2 | 18 | Pastor Maldonado | Williams | 1:23.380 | 1:22.105 | 1:22.285 | 14 | |
| 3 | 5 | Fernando Alonso | Ferrari | 1:23.276 | 1:22.862 | 1:22.302 | 15 | |
| 4 | 10 | Romain Grosjean | Lotus | 1:23.248 | 1:22.667 | 1:22.424 | 14 | |
| 5 | 9 | Kimi Räikkönen | Lotus | 1:23.406 | 1:22.856 | 1:22.487 | 13 | |
| 6 | 15 | Sergio Pérez | Sauber | 1:24.261 | 1:22.773 | 1:22.533 | 14 | |
| 7 | 8 | Nico Rosberg | Mercedes | 1:23.370 | 1:22.882 | 1:23.005 | 17 | |
| 8 | 1 | Sebastian Vettel | Red Bull | 1:23.850 | 1:22.884 | 14 | ||
| 9 | 7 | Michael Schumacher | Mercedes | 1:23.757 | 1:22.904 | 15 | ||
| 10 | 14 | Kamui Kobayashi | Sauber | 1:23.386 | 1:22.897 | 14 | ||
| 11 | 3 | Jenson Button | McLaren | 1:23.510 | 1:22.944 | 13 | ||
| 12 | 2 | Mark Webber | Red Bull | 1:23.592 | 1:22.977 | 8 | ||
| 13 | 11 | Paul di Resta | Force India | 1:23.852 | 1:23.125 | 14 | ||
| 14 | 12 | Nico Hülkenberg | Force India | 1:23.720 | 1:23.177 | 13 | ||
| 15 | 17 | Jean–Éric Vergne | Toro Rosso | 1:24.362 | 1:23.265 | 11 | ||
| 16 | 16 | Daniel Ricciardo | Toro Rosso | 1:23.906 | 1:23.442 | 11 | ||
| 17 | 6 | Felipe Massa | Ferrari | 1:23.886 | 1:23.444 | 12 | ||
| 18 | 19 | Bruno Senna | Williams | 1:24.981 | 8 | |||
| 19 | 21 | Vitaly Petrov | Team Caterham | 1:25.277 | 8 | |||
| 20 | 20 | Heikki Kovalainen | Team Caterham | 1:25.507 | 8 | |||
| 21 | 25 | Charles Pic | Marussia | 1:26.582 | 8 | |||
| 22 | 24 | Timo Glock | Marussia | 1:27.032 | 8 | |||
| 23 | 22 | Pedro de la Rosa | HRT | 1:27.555 | 6 | |||
| 24 | 23 | Narain Karthikeyan | HRT | 1:31.122 | 4 | |||
| 107% | 1:28.363 |
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