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Vítězem druhého volného tréninku v kanadském Montrealu se stal opět Lewis Hamilton. Za ním se seřadilo duo jezdců stáje Ferrari v pořadí Alonso a Massa.
| P | # | Jezdec | Konstruktér | Čas | K | |
|---|---|---|---|---|---|---|
| 1 | 4 | Lewis Hamilton | McLaren | 1:15.259 | 43 | |
| 2 | 5 | Fernando Alonso | Ferrari | 1:15.313 | 36 | |
| 3 | 6 | Felipe Massa | Ferrari | 1:15.410 | 39 | |
| 4 | 1 | Sebastian Vettel | Red Bull | 1:15.531 | 44 | |
| 5 | 11 | Paul di Resta | Force India | 1:15.544 | 32 | |
| 6 | 14 | Kamui Kobayashi | Sauber | 1:15.651 | 37 | |
| 7 | 7 | Michael Schumacher | Mercedes | 1:15.697 | 32 | |
| 8 | 12 | Nico Hülkenberg | Force India | 1:15.799 | 39 | |
| 9 | 3 | Jenson Button | McLaren | 1:15.812 | 14 | |
| 10 | 8 | Nico Rosberg | Mercedes | 1:15.878 | 40 | |
| 11 | 15 | Sergio Pérez | Sauber | 1:15.898 | 38 | |
| 12 | 2 | Mark Webber | Red Bull | 1:15.907 | 41 | |
| 13 | 18 | Pastor Maldonado | Williams | 1:15.987 | 39 | |
| 14 | 10 | Romain Grosjean | Lotus | 1:16.360 | 29 | |
| 15 | 9 | Kimi Räikkönen | Lotus | 1:16.562 | 33 | |
| 16 | 20 | Heikki Kovalainen | Team Caterham | 1:16.981 | 24 | |
| 17 | 19 | Bruno Senna | Williams | 1:17.022 | 22 | |
| 18 | 21 | Vitaly Petrov | Team Caterham | 1:17.075 | 41 | |
| 19 | 17 | Jean–Éric Vergne | Toro Rosso | 1:17.124 | 41 | |
| 20 | 16 | Daniel Ricciardo | Toro Rosso | 1:17.716 | 34 | |
| 21 | 22 | Pedro de la Rosa | HRT | 1:18.908 | 27 | |
| 22 | 24 | Timo Glock | Marussia | 1:19.084 | 40 | |
| 23 | 23 | Narain Karthikeyan | HRT | 1:19.378 | 21 | |
| 24 | 25 | Charles Pic | Marussia | 1:19.902 | 18 |
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